Ceramic Interfaces - Properties and Applications

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CEAS Library Resources in Materials Science -- Ceramics

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CEAS Library Resources in Materials Science -- Ceramics

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Ceramic Interfaces: Properties and Applications

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Surfaces and Interfaces of Ceramic Materials | SpringerLink

Non-UNL users: Please talk to your librarian about requesting this dissertation through interlibrary loan. Victor Curicuta , University of Nebraska - Lincoln. In this research work, results are reported for direct bonding of copper to ceramic e. All these experiments were performed by heating the metal or metal-organic media member for a sufficient time in order to create a metal-metal oxide eutectic melt at the interface with the ceramic substrate. It was found that the method of direct bonding of metals to ceramics using lasers performed better than the furnace.

The properties of the copper bonded layer on alumina ceramic was investigated using scanning electron microscopy SEM. It was found that the samples processed by furnace heating and by laser beam heating have a diffused transition interface. The TEM images show that the samples heated using excimer laser have an amorphous top copper layer.

In order to investigate inter-diffusion between the copper layer and the sapphire and also to measure the percentage of diffused of copper in sapphire, Rutherford backscattering spectroscopy RBS was performed. Based on heat transfer theory and on diffusion theory, a model was derived to explain and predict the behavior of furnace and laser beam bonding of metals to ceramics.

The predictions of the model were in agreement with the experimental percentage values of diffused copper in sapphire obtained in the RBS investigations. Experimental investigations and the theoretical model concluded that the direct bonding phenomenon is a thermal effect.